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Ordered Ag composite electrode for an efficient alkaline hydrogen evolution reaction

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Abstract

Develo** active, durable, and cost-controllable catalytic electrodes is the key of efficiently convert and store sustainable energy of hydrogen, but still a great challenge. Herein, we prepared a new Ag-based composite electrode of NiO/Ag and CuO/Ag by a facile method, which had a special through-hole-ordered structure for high-efficiency hydrogen evolution reaction (HER) in alkaline media. Of them, the NiO/Ag electrode showed excellent electrocatalytic performance, with an extremely low overpotential of 23 mV at a current density of 10 mA cm−2, as well a small Tafel slope of 73.2 mV dec−1, which exhibited comparable or better performance than the other state-of-the-art Ag-based electrodes for HER. The composite electrodes were characterized and the reaction mechanism was discussed. It is proposed that the heterojunction on the interface of NiO with Ag decreased the binding energy and charge density of Ag. Particularly, the through-hole-ordered structure provided more reactive sites and accelerated species transfer and water decomposition reaction.

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Acknowledgements

The work was financially supported by the Key Laboratory of Photochemical Conversion and Optoelectronic Materials and the Technical Institute of Physical and Chemistry, Chinese Academy of Sciences, China.

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Authors and Affiliations

  1. Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Bei**g, 100190, China

    Hao Huo, Hua Tian, Shidong Nie, Qiuyun He, Zhiying Zhang & Chunyan Liu

  2. University of Chinese Academy of Sciences, Bei**g, 100049, China

    Hao Huo

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  1. Hao Huo
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  2. Hua Tian
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  4. Qiuyun He
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Contributions

HH conceived the idea and performed the experiments and wrote the initial draft of the manuscript. HT, SN, and He Q supervised the experiment and characterization. Zhang Z provided analysis tools. Zhang Z and Lin C revised the manuscript and supervised the analysis. All authors contributed to the general discussion.

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Correspondence to Zhiying Zhang or Chunyan Liu.

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Huo, H., Tian, H., Nie, S. et al. Ordered Ag composite electrode for an efficient alkaline hydrogen evolution reaction. J Mater Sci: Mater Electron 34, 1223 (2023). https://doi.org/10.1007/s10854-023-10641-1

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